文献类型： 外文期刊

作者： Lan, Guanyu ¹ ; Li, Xue ² ; Yao, Jijun ³ ; Yu, Xiaofeng ³ ; Liu, Qinghai ¹ ; Qiu, Cheng ¹ ; Mao, Xuefei ² ;

作者机构： 1.Tibet Acad Agr & Anim Husb Sci, Inst Agr Prod Qual Stand & Testing Res, Lhasa, Xizang, Peoples R China

2.Chinese Acad Agr Sci, Inst Qual Stand & Testing Technol Agroprod, Key Lab Agrofood Safety & Qual, Minist Agr & Rural Affairs, Beijing, Peoples R China

3.Hangzhou Puyu Technol Co Ltd, Hangzhou, Zhejiang, Peoples R China

关键词： selenium; heavy metals; electrothermal vaporization; slurry sampling; signal delay device; inductively coupled plasma mass spectrometry

期刊名称：FRONTIERS IN NUTRITION （ 影响因子：5.0； 五年影响因子：5.7 ）

ISSN： 2296-861X

年卷期： 2023 年 10 卷

页码：

收录情况： SCI

摘要： Rapid, sensitive and simultaneous determination of trace multi-elements in various plant food samples such as grain, oilseed, vegetable and tea is always a challenge thus far. In this work, a rapid determination method for Se, Cd, As and Pb in food samples by inductively coupled plasma mass spectrometry (ICP-MS) using slurry sampling electrothermal vaporization (SS-ETV) was developed. To improve the analytical sensitivity and precision as well as eliminate the memory effect, a gas turbulator line and signal delay device (SDD) were for the first time designed for the graphite furnace (GF) ETV coupled with ICP-MS. The signal acquisition parameters of ICP-MS, ashing and vaporization conditions, and the flow rates of carrier gas and gas turbulator were investigated for Se, Cd, As and Pb in food samples. Under the optimized conditions, the limits of determination (LODs) for Se, Cd, As and Pb were 0.5 ng g(-1), 0.3 ng g(-1), 0.3 ng g(-1) and 0.6 ng g(-1), respectively; the limits of quantification (LOQs) for Se, Cd, As and Pb were 1.7 ng g(-1), 1.0 ng g(-1), 1.0 ng g(-1) and 1.9 ng g(-1), respectively; linearity (R-2) in the range of 1 to 4,000 ng g(-1) was >0.999 using the standard addition method. This method was used to analyze 5 CRMs including rice, tea and soybeans, and the concentrations detected by this method were within the range of the certified values. The recoveries of Se, Cd, As and Pb in plant food matrices including grain, oilseed, celery, spinach, carrot and tea samples were 86-118% compared to the microwave digestion ICP-MS method; and the relative standard deviations (RSDs) were 1.2-8.9% for real food sample analysis, proving a good precision and accuracy for the simultaneous determination of multi-elements. The analysis time was less than 3 min, slurry preparation time < 5 min without sample digestion process. The proposed direct slurry sampling ICP-MS method is thus suitable for rapid and sensitive determination of Se, Cd, As and Pb in food samples with advantages such as simplicity, green and safety, as well as with a promising application potential in detecting more elements to protect food safety and human health.